Experimental and theoretical studies on the spontaneous ignition proce
ss of isolated fuel droplets were carried out. Time dependent temperat
ure fields around the igniting droplets were observed by interferometr
y so that two step temperature rise can be detected. Some experiments
are performed under microgravity to obtain reference data. Induction t
imes are examined as a function of ambient temperature. As a result, a
zero temperature coefficient region is found, which is equivalent to
the NTC (negative temperature coefficient) region for the ignition of
premixed gas. A numerical model is developed applying a simplified che
mical reaction model that includes the low and the high temperature re
actions. The model is able to reproduce the two step temperature rise
and the roles of the two kinds of reactions on the ignition process up
to the establishment of a diffusion flame around the droplet are exam
ined.