IN-SITU ANALYSIS OF RU CARBONYL CATALYSTS FOR CARBONYLATION REACTIONSBY FOURIER-TRANSFORM INFRARED SPECTROMETRY

Authors
KAIHARA M MAMETSUKA H GUNJI N NAKAMURA T IKARIYA T GOHSHI Y
Citation
M. Kaihara et al., IN-SITU ANALYSIS OF RU CARBONYL CATALYSTS FOR CARBONYLATION REACTIONSBY FOURIER-TRANSFORM INFRARED SPECTROMETRY, SPECT ACT A, 52(2), 1996, pp. 167-171
Citations number
9
Categorie Soggetti
Spectroscopy
Journal title
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY → ACNP
ISSN journal
13861425
Volume
52
Issue
2
Year of publication
1996
Pages
167 - 171
Database
ISI
SICI code
1386-1425(1996)52:2<167:IAORCC>2.0.ZU;2-F
Abstract
When using Ru complexes as catalysts for carbonylation reactions under the conditions of high temperature and high pressure, we sequentially measured in situ IR spectra during the synthesis, and respectively an alyzed the complicated behavior of several Ru complexes by applying co mponent seperation analysis (inverse problems). This kind of analysis, combining in situ measurements and component separation analysis, cou ld be a promising characterization technique for optically homogeneous catalysts.