Sl. Wu et al., SYNTHESIS AND CHARACTERIZATION OF FERROELECTRIC AND ANTIFERROELECTRICLIQUID-CRYSTALS DERIVED FROM (2S)-2-(6-HYDROXY-2-NAPHTHYL)PROPIONIC ACID, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 264, 1995, pp. 39-50
A new series of chiral materials, hexy](2s)-2-(6-(-4-(4'-alkoxyphenyl)
benz propionates (HmPBNP; m = 6-18) had been prepared and their liquid
crystalline properties were investigated as a function of alkyl chain
length. These chiral materials exhibited novel ferroelectric S-c and
antiferroelectric Sc-A phases and a propensity to the formation of t
he Sc-A phase was found at longer alkyl chain lengths (m = 10, 12-18)
. An odd-even effect of the threshold voltage as a function of alkyl c
hain length for compounds HmPBNP (m = 12-16) possessing antiferroelect
ricity was observed. Spontaneous polarization and trans verse dipole m
oment were also measured and are discussed in terms of the elongated a
lkyl chain length.