S. Higo et al., RAPIDLY ANNEALED BI(PB)SRCACUO THIN-FILMS PREPARED BY A 2223-STOICHIOMETRIC TARGET SPUTTERING, International journal of modern physics b, 10(8), 1996, pp. 957-966
Thin films of BiSrCaCuO were prepared on MgO (100) by a single target
sputtering. This deposition process yielded c-axis oriented supercondu
cting thin films with a smooth surface. The as-grown films grown at 67
0-690 degrees C showed 2223 single phase and zero resistivity at about
60 Ii. The as-grown films were directly placed on a Bi(Pb)SrCaCuO bul
l; sample, and then rapidly annealed at 835-845 degrees C within 40 s
in air. The superconducting properties of the annealed Bi(Pb)SrCaCuO f
ilms were greatly improved by optimizing the temperature and time duri
ng rapid annealing. Films annealed at 840 degrees C for 30 s in air sh
owed zero resistivity at 100 K and had the critital current of about 1
x 10(6) A/cm(2) at 77 K. The surfaces of these films on MgO were blac
k and smooth. The film quality is greatly improved by means of anneali
ng process at 840 degrees C for a very short time of 30 s in air after
deposition.