This paper investigates the role of a nonzero vapour entry pressure on
reservoir storage and containment of the greenhouse gas carbon dioxid
e. Two effects are observed: vapour storage under confining layers, an
d enhanced lateral spreading of gas under confining layers. Lateral fl
ow of gas under both impermeable and permeable confining layers is sol
ved analytically using Buckley-Leverett assumptions. A full numerical
analysis of gas and water transport is also presented, using results f
rom the simulator TOUGH. We consider the injection of CO2 from a therm
al power plant at a rate of 100 kg/s for 10 years, at a depth of 3000
metres. Inclusion of a nonzero vapour entry pressure shows that contai
nment of this gas for at least 5000 years can be expected. The CO2 is
stored predominantly in a high density vapour phase (about 600 kg/m(3)
) under lower permeability confining layers, and also is dissolved in
liquid at about 40 kg/m(3).