SYNTHESIS OF L-2,3,4,5-TETRAHYDRO-2,5-METHANO-1H-2-BENZAZEPINES AND THEIR REARRANGEMENT TO O-1,2,3,4,5,6-HEXAHYDRO-2,6-METHANO-2-BENZAZOCINES

Authors
BLOUGH BE MASCARELLA SW ROTHMAN RB CARROLL FI
Citation
Be. Blough et al., SYNTHESIS OF L-2,3,4,5-TETRAHYDRO-2,5-METHANO-1H-2-BENZAZEPINES AND THEIR REARRANGEMENT TO O-1,2,3,4,5,6-HEXAHYDRO-2,6-METHANO-2-BENZAZOCINES, Journal of the Chemical Society, Chemical Communications, (9), 1993, pp. 758-760
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
9
Year of publication
1993
Pages
758 - 760
Database
ISI
SICI code
0022-4936(1993):9<758:SOLAT>2.0.ZU;2-L
Abstract
This study reports a three-step synthesis of 3-halomethyl-2,3,4,5-tetr ahydro-2,5-methano-1 H-2-benzazepines 2a-c and the rearrangement of 2a -b to 4-iodo- and 5,6-hexahydro-2,6-methano-2-methano-2-benzazocines 1 a-b.