Rd. Weir et Rn. Goldberg, ON THE CONVERSION OF THERMODYNAMIC PROPERTIES TO THE BASIS OF THE INTERNATIONAL TEMPERATURE SCALE OF 1990, Journal of Chemical Thermodynamics, 28(3), 1996, pp. 261-276
The basis and application of the Douglas equations for the adjustment
and calculation of differences in thermodynamic properties due to a ch
ange in the temperature scale are reviewed. When higher-order terms in
the general Douglas equations are discarded, the simplified Douglas e
quations are obtained. These simplified equations together with the re
cently revised set of differences between values of temperatures on th
e International Temperature Scale of 1990 (ITS-90) and the correspondi
ng values on the International Practical Temperature Scale of 1968 (IP
TS-68) for 903.765 K < T-90 < 1337.33 K have been used to calculate ap
proximate differences in thermodynamic properties for synthetic sapphi
re (alpha-Al2O3). Tables of differences (T-90-T-68)/K and the derivati
ves d(T-90-T-68)/dT are given as a function of T-68/K. (C) 1996 Academ
ic Press Limited