ANISOTROPY OF OF CHI((3)) OF TIN-PHTHALOCYANINE DEPOSITION FILM

Citation
M. Yamashita et al., ANISOTROPY OF OF CHI((3)) OF TIN-PHTHALOCYANINE DEPOSITION FILM, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 267, 1995, pp. 77-82
Citations number
6
Categorie Soggetti
Crystallography
ISSN journal
1058725X
Volume
267
Year of publication
1995
Pages
77 - 82
Database
ISI
SICI code
1058-725X(1995)267:<77:AOOCOT>2.0.ZU;2-E
Abstract
Third-order electric susceptibility chi((3)) of tin-phthalocyanine fil m deposited on a boro-silicated glass plate coated with rubbing-treate d polyimide thin film was measured by a method of THG Maker-fringe tec hnique. In the resonant absorption spectral range, the maximum values of chi((3)) of aggregated tin-phthalocyanine were 220x10(-12)esu obtai ned in the direction perpendicular to the rubbing direction, but the v alues parallel to the rubbing were 47x10(-12)esu. The large \ anisotro py of chi((3)) was induced by a preferred orientation of tin-phthalocy anine microcrystals when anisotropic substrates were heated at 200 deg rees C.