M. Kiguchi et al., OBSERVATION OF 3RD-HARMONIC GENERATION IN POLYDIACETYLENE FILMS USINGINTERNAL-REFLECTION GEOMETRY, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 267, 1995, pp. 101-106
We have demonstrated technique for measuring the third-order nonlinear
optical susceptibility chi((3))(-3 omega;omega,omega,omega) based on
internal reflection. Using this technique, we observed third-harmonic
generation from a poly-DCH film deposited on oriented LB film of poly(
3BCMU). Its chi((3)) was 2.1 times as large as an another film with no
LB film. This suggests that the oriented LB film contributes to the a
lignment of the DCH monomer deposited on it.