POLYMERS FROM RENEWABLE RESOURCES .7. THERMAL-PROPERTIES OF THE SEMIINTERPENETRATING POLYMER NETWORKS COMPOSED OF CASTOR-OIL POLYURETHANES AND CARDANOL-FURFURAL RESIN
Dk. Mishra et al., POLYMERS FROM RENEWABLE RESOURCES .7. THERMAL-PROPERTIES OF THE SEMIINTERPENETRATING POLYMER NETWORKS COMPOSED OF CASTOR-OIL POLYURETHANES AND CARDANOL-FURFURAL RESIN, Polymer engineering and science, 36(8), 1996, pp. 1047-1051
A number of semi-interpenetrating polymer networks (semi-IPNs) were sy
nthesized by reacting polyurethanes (prepared from castor oil and vari
ous diisocyanates) and a phenolic resin (prepared from cardanol and fu
rfural). The physico-chemical properties of the semi-IPNs have been in
vestigated. The thermogravimetric analysis of polymers was followed us
ing a computer analysis method for assigning the kinetic mechanism. Va
rious kinetic equations have been used to evaluate the kinetic paramet
ers. The suggested mechanism of degradation of the semi-IPNs is based
on the kinetic parameters.