INTERACTIONS IN LA(III) ND(III) SM(III) RB(I) CS(I) AND PD(II) REINECKATES

New reineckates La(III), Nd(III), Sm(III) and Rb(I) and spectroscopica lly not investigated reineckates Pd(II) and Cs(I) were synthesized. Sp ectral investigations (VIS, IR, EPR) have shown that bridges of Cr-NCS -M and Cr-NCS-H-O-H type occur in the modes of crystal lattice. It has been proved that in reineckates Pd(II), Cs(I), Rb(I) spin-orbital cou plings dominate over crystallic field effect of ion Cr(III), while in reineckates La(III), Nd(III), Sm(III) dipole-dipole interactions exist .