A. Grodzicki et P. Piszczek, THE BENDING FREQUENCIES OF WATER-MOLECULES IN DIFFERENT CRYSTAL SURROUNDINGS, Polish Journal of Chemistry, 70(5), 1996, pp. 620-631
A detailed study of the infrared spectra of crystalline hydrates and a
quo-complexes were performed to characterize the water molecules inter
action in the crystal lattice. Water molecules form a special arrangem
ents in the unit cell, that causes characteristic changes of delta(HOH
) band parameters in the range 1500-1800 cm(-1). Basing on the spectra
of solid hydrates with known crystal structure, criteria of estimatio
n of these interactions have been presented.