RADICAL CATIONS OF QUADRICYCLANE AND NORBORNADIENE IN POLAR ZSM-5 MATRICES - THERMAL RETRO-DIELS-ALDER REACTION

Authors
BARNABAS MV TRIFUNAC AD
Citation
Mv. Barnabas et Ad. Trifunac, RADICAL CATIONS OF QUADRICYCLANE AND NORBORNADIENE IN POLAR ZSM-5 MATRICES - THERMAL RETRO-DIELS-ALDER REACTION, Journal of the Chemical Society, Chemical Communications, (10), 1993, pp. 813-814
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
10
Year of publication
1993
Pages
813 - 814
Database
ISI
SICI code
0022-4936(1993):10<813:RCOQAN>2.0.ZU;2-Z
Abstract
The radical cation of norbornadiene or quadricyclane (Q) and of norbor nadiene (NBD) produced by gamma-radiolysis in polar ZSM-5 undergo a re verse Diels-Alder reaction, which is a thermally forbidden, photochemi cally allowed process, to cyclopentadiene radical cation.