V. Rusanov et al., DETERMINATION OF THE MOSSBAUER PARAMETERS OF NITROSYLPENTACYANOFERRATES (NP), Journal of solid state chemistry, 123(1), 1996, pp. 39-47
The Mossbauer parameters isomer shift (IS), quadrupole splitting (QS),
and probability of recoilless absorption f' of 26 nitroprussides have
been measured at room and liquid nitrogen temperatures. The values of
the QS and the IS of the different compounds are close to each other,
which is supposed to result from the same short-range environment of
the Fe atom in the [Fe(CN)(5)NO](2-) ion. A weak correlation between I
S and electronegativity of the lattice cation, as well as between QS a
nd CNtrans stretching vibrations was found. For some of the investigat
ed nitroprussides a Goldanskii-Karyagin effect was observed. The Mossb
auer parameters IS and QS for two long-living electronic metastable co
nfigurations in some nitroprusside single crystals are measured, too.
Like in the case of ground state, these parameters are very close to e
ach other, which shows that for the new metastable states the changes
in the electron density distribution of the [Fe(CN)(5)NO](2-) anion do
not practically depend on the kind of the metal cation. (C) 1996 Acad
emic Press, Inc.