Wa. Moseley et Vk. Dhir, CAPILLARY PRESSURE-SATURATION RELATIONS IN POROUS-MEDIA INCLUDING THEEFFECT OF WETTABILITY, Journal of hydrology, 178(1-4), 1996, pp. 33-53
In this work a functional relationship between capillary pressure and
wetting phase saturation has been developed. Both the imbibition and d
rainage of a wetting phase liquid into a porous medium consisting of c
lean unconsolidated silica particles have been considered. In all, two
bead packings, with average particle diameters of 120 mu m and 360 mu
m, and three liquids-water, ethanol, and refrigerant-113-were studied
. It was found that the Leverett function worked very well in describi
ng the relation between capillary pressure and saturation for each liq
uid using both packings; however, it did not provide adequate correlat
ion for all three liquids. The functional relationship presented here
considers the dependence of capillary pressure upon the contact angle
of the fluid-solid interface, and also conveys how this dependence var
ies with saturation. The inclusion of the contact angle dependence pro
vides extension of the correlation to any wetting phase liquid of unif
orm properties.