Jk. Walters et al., A NEUTRON AND X-RAY-DIFFRACTION STUDY OF THE INFLUENCE OF DEPOSITION CONDITIONS ON THE STRUCTURE OF A-C-H, Journal of non-crystalline solids, 197(1), 1996, pp. 41-52
The atomic scale structure of amorphous hydrogenated carbon (a-C:H) fi
lms prepared from an acetylene precursor by plasma enhanced chemical v
apour deposition (PECVD) and a fast-atom source (FAS) have been studie
d by neutron and X-ray diffraction. The effect of beam energy on the s
tructure of the film is investigated, and comparison is made to sample
s prepared using at fast atom (neutral particle) source, also using ac
etylene as the precursor, The results show that, in both deposition me
thods, increasing the beam energy produces a lower total sp(2) hybridi
sed carbon content in the film with evidence for a shift from pure ole
finic to some aromatic/graphitic bonding in the FAS samples. The high
resolution real-space neutron diffraction data allows a direct determi
nation of the single:double bond ratio, and also shows the presence of
sp(1) hybridised carbon bonding environments.