STUDIES ON THE NITROSATION OF N-SILYLATED CYCLOPENTENYLAMINES

Citation
Rm. Alvarez et al., STUDIES ON THE NITROSATION OF N-SILYLATED CYCLOPENTENYLAMINES, Journal of physical organic chemistry, 9(4), 1996, pp. 227-233
Citations number
16
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
ISSN journal
08943230
Volume
9
Issue
4
Year of publication
1996
Pages
227 - 233
Database
ISI
SICI code
0894-3230(1996)9:4<227:SOTNON>2.0.ZU;2-M
Abstract
The diazotization of N-silylated N-methyl- and N-phenylcyclopentenylam ines affords products derived from intermediate methyl- and phenyldiaz onium ions. However, when this method is applied to N,N-bissilylated c yclopentenylamines, the products obtained do not confirm the formation of a cyclopentenyl cation intermediate.