USE OF MENO(2)-LICLO4 IN PROMOTING A 1,2-SHIFT IN RSCL ELECTROPHILIC ADDITION TO 3,3-DIMETHYLBUT-1-ENE - REACTION COURSE AND STEREOCHEMISTRY

Authors
BORISOV AB BODRIKOV IV BORISOVA GN BELSKY VK SMIT WA LUTSENKO AI
Citation
Ab. Borisov et al., USE OF MENO(2)-LICLO4 IN PROMOTING A 1,2-SHIFT IN RSCL ELECTROPHILIC ADDITION TO 3,3-DIMETHYLBUT-1-ENE - REACTION COURSE AND STEREOCHEMISTRY, Mendeleev communications, (2), 1996, pp. 52-53
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
2
Year of publication
1996
Pages
52 - 53
Database
ISI
SICI code
0959-9436(1996):2<52:UOMIPA>2.0.ZU;2-K
Abstract
In the Ad(E) reaction of RSCI with 3,3-dimethylbut-1-ene the system Me NO(2)-LiClO4 serves as an efficient promoter of a 1,2-shift which occu rs either simultaneously with the electrophilic addition step (pi-rout e) or as a rearrangement of the initially-formed 1,2-adducts (sigma-ro ute) and proceeds in a highly stereoselective fashion.