FERROMAGNETIC INTERACTIONS IN A DECAMETHYLFERROCENIUM SALT OF NICKEL(III) BIS(2-OXO-1,3-DITHIOLE-4,5-DITHIOLATE)

Authors
FETTOUHI M OUAHAB L CODJOVI E KAHN O
Citation
M. Fettouhi et al., FERROMAGNETIC INTERACTIONS IN A DECAMETHYLFERROCENIUM SALT OF NICKEL(III) BIS(2-OXO-1,3-DITHIOLE-4,5-DITHIOLATE), Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 273, 1995, pp. 29-33
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
273
Year of publication
1995
Pages
29 - 33
Database
ISI
SICI code
1058-725X(1995)273:<29:FIIADS>2.0.ZU;2-U
Abstract
The synthesis, crystal structure and magnetic properties of the title compound are presented : Fe[C-5(CH3)(5)](2)[Ni(III)(S4C3O)(2)](CH3CN), Mr = 786.65, crystallizes in the C2/m monoclinic space group with cel l parameters a=16.374(4) Angstrom, b=10.84(2)Angstrom, c=19.530(5)Angs trom, beta=98.02(2)degrees, V = 3431 Angstrom(3), Z=4, d(calc)= 1.523 g . cm(-3), Full-matrix least-squares refinements gave R(F)=0.060, Rw( F)=0.077 based on 1068 reflections with I>3 sigma(I). The magnetic beh avior is typical of dominant ferromagnetic interactions to which very weak antiferromagnetic interactions are superimposed.