In this letter, we report the results of ion implantation of GaN using
Si-28 and Mg-24 species. Structural and electrical characterizations
of the GaN thin films after thermal annealing show that native defects
in the GaN films dominate over implant doping effects. The formation
energies of the annealing induced defects are estimated to range from
1.4 to 3.6 eV. A 40 keV 10(14) cm(-2) Mg implant results in the decrea
se of the free-carrier concentration by three orders of magnitude comp
ared to unimplanted GaN up to an annealing temperature of 690 degrees
C. Furthermore, we have observed the correlation between these anneali
ng-induced defects to both improved optical and electrical properties.
(C) 1995 American Institute of Physics.