A polymer light-emitting electrochemical cell (LEC) is a bipolar p-n j
unction device; when biased, a dynamic light-emitting p-n junction is
created. In this letter, we report a two color LEC in which the color
can be switched by simply reversing the bias voltage. The two color LE
C consists of a polymer bilayer structure sandwiched between two elect
rodes. In this study, the polymer bilayer consists of a poly(1,4-pheny
lene vinylene) (PPV) layer and a poly[2-methoxy-5-(2'-ethylhexyloxy)-1
,4-phenylene vinylene] (MEH-PPV) layer. When biased at one polarity, t
he voltage induced p-n junction is completely inside the PPV layer, an
d the LEC emits the green light of PPV. When biased at the opposite po
larity, the p-n junction is completely inside the MEH-PPV layer, and t
he LEC emits the orange light characteristic of MEH-PPV. (C) 1996 Amer
ican Institute of Physics.