The structure and energetics of protonated p-benzoquinone (pBQ) have b
een investigated using high-pressure mass spectrometry and ab initio c
alculations. The experimental proton affinity of pBQ is 801.4 +/- 8.9
kJ/mol (191.5 +/- 2.1 kcal/mol) (1 sigma) from bracketing measurements
and hydration thermochemistry. This value is supported by theory and
by analogies with related compounds. In its protonation chemistry, pBQ
behaves as an aliphatic ketone, both structurally and energetically.
The dissociation of the hydrate (pBQH(+)).(H2O) is characterized by De
lta H degrees(D) = 90.0 +/- 2.3 kJ/mol and Delta S degrees D = 123.4 /- 4.9 J/mol . K (95% confidence).