THE FIRST STEREOSPECIFIC SYNTHESIS OF MICHELLAMINE-B

Authors
HOBBS PD UPENDER V LIU JW POLLART DJ THOMAS DW DAWSON MI
Citation
Pd. Hobbs et al., THE FIRST STEREOSPECIFIC SYNTHESIS OF MICHELLAMINE-B, Chemical communications, (8), 1996, pp. 923-924
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
8
Year of publication
1996
Pages
923 - 924
Database
ISI
SICI code
1359-7345(1996):8<923:TFSSOM>2.0.ZU;2-W
Abstract
The dimeric alkaloid michellamine B is synthesized stereospecifically by the palladium-catalysed cross-coupling of the 6'-naphthaleneboronic acid of the tetrabenzylated derivative of korupensamine A and the 6'- bromo analogue of the tetrabenzylated derivative of korupensamine B, b oth of which are prepared by total synthesis.