PHOTOCHEMICAL INTERMOLECULAR C-H AND C-F INSERTION OF RHODIUM INTO PENTAFLUOROANISOLE TO GENERATE A METALLACYCLE - CONVERSION TO A CYCLIC CARBENE COMPLEX

Authors
BALLHORN M PARTRIDGE MG PERUTZ RN WHITTLESEY MK
Citation
M. Ballhorn et al., PHOTOCHEMICAL INTERMOLECULAR C-H AND C-F INSERTION OF RHODIUM INTO PENTAFLUOROANISOLE TO GENERATE A METALLACYCLE - CONVERSION TO A CYCLIC CARBENE COMPLEX, Chemical communications, (8), 1996, pp. 961-962
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
8
Year of publication
1996
Pages
961 - 962
Database
ISI
SICI code
1359-7345(1996):8<961:PICACI>2.0.ZU;2-0
Abstract
Irradiation of [(eta(5)-C5H5)Rh(PMe(3))(C2H4)] in pentafluoroanisole g enerates the metallacycle [(eta(5)-C5H5)(PMe(3))RhCH(2)OC(6)F4]; react ion of this complex with 1 equiv, of Ph(3)C(+)PF6(-) at 220 K generate s [(eta(5)-C5H5)(PMe(3))Rh=C(H)OC6F4]PF6.