THE NOVEL MAGNETIC-PROPERTIES OF SSSNCCNSSS(M)(2) (M=ASF6, SB2F11) AND THE ELECTRONIC-PROPERTIES OF (SSSNCCNSSS-DOT)-S-CENTER-DOT+(CENTER)

Authors
ENRIGHT GD MORTON JR PASSMORE J PRESTON KF THOMPSON RC WOOD DJ
Citation
Gd. Enright et al., THE NOVEL MAGNETIC-PROPERTIES OF SSSNCCNSSS(M)(2) (M=ASF6, SB2F11) AND THE ELECTRONIC-PROPERTIES OF (SSSNCCNSSS-DOT)-S-CENTER-DOT+(CENTER), Chemical communications, (8), 1996, pp. 967-968
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
8
Year of publication
1996
Pages
967 - 968
Database
ISI
SICI code
1359-7345(1996):8<967:TNMOS(>2.0.ZU;2-1
Abstract
The variable-temperature magnetic behaviour of the previously reported AsF6- and presently reported Sb2F11-salts of bis(1,2,3,4-trithiazoliu m), (SSSNCCNSSS+.)-S-.+ (1(2+)), are complex but indicate intermolecul ar antiferromagnetic interactions and temperature-independent paramagn etism, as well as intramolecular antiferromagnetic coupling leading to a singlet ground state, with a nearly degenerate thermally accessible triplet excited state, which is confirmed by EPR spectroscopy.