Jg. Muga et al., COMPARISON OF POSITIVE FLUX OPERATORS FOR TRANSITION-STATE THEORY USING A SOLVABLE MODEL, The Journal of chemical physics, 104(18), 1996, pp. 7015-7026
Several quantum operators representing ''positive flux'' are compared
for the square barrier by examining their ability to reproduce the exa
ct transmittance when traced with the exact microcanonical density ope
rator. They are obtained by means of the ''Weyl rule,'' the ''Rivier r
ule,'' by symmetrizing the product of ''flux'' and ''positive momentum
projection'' operators, acid by a variational technique. Explicit exp
ressions are given for all cases. (C) 1996 American Institute of Physi
cs.