DETERMINATION OF MICROAMOUNTS OF RUTHENIUM(III) BY THE SOLID-LIQUID EXTRACTION METHOD

Authors
CHEN XG WANG XJ HU Z
Citation
Xg. Chen et al., DETERMINATION OF MICROAMOUNTS OF RUTHENIUM(III) BY THE SOLID-LIQUID EXTRACTION METHOD, Analytical letters, 29(6), 1996, pp. 1003-1012
Citations number
8
Categorie Soggetti
Chemistry Analytical
Journal title
Analytical letters → ACNP
ISSN journal
00032719
Volume
29
Issue
6
Year of publication
1996
Pages
1003 - 1012
Database
ISI
SICI code
0003-2719(1996)29:6<1003:DOMORB>2.0.ZU;2-5
Abstract
The new favorable distribution equilibrium of the complex of Ru(III)-c hrome azurol S between the solid and liquid phases of Tween 80-(NH4)(2 )SO4-H2O extraction system was investigated. The extraction efficiency (%E), distribution coefficient and concentration factors are studied. Spectrophotometric characteristics of the complex in such a system ar e stable. This method was used to determine microamounts of ruthenium( III) in secondary alloys of Ni. This method of extraction overcomes ma ny disadvantages of methods using usual organic reagents as solvents.