A layer of fluid lies between two parallel horizontal walls and the so
lute concentration and temperature are higher at the bottom wall. The
onset of time-periodic instability in this double diffusion problem in
three dimensions is analyzed. Periodicity with respect to the hexagon
al lattice is assumed. The no-slip condition is imposed at the top and
bottom boundaries. There are 11 bifurcating solutions, and their stab
ility is presented. For relatively low solutal and thermal Rayleigh nu
mbers, the solutions are found to be unstable. For the heating of salt
y water, situations are presented where the standing rolls, the standi
ng patchwork quilt, and either the standing hexagons or the standing r
egular triangles, may be stable.