Photoemission spectra from thin films of KxC60 prepared by vapor-phase
reaction of C60 with K vapor consist of superpositions of distinct bu
lk and surface contributions. The spectra of K3C60 and K6C60 are ident
ified and shown to be in very good agreement with band-structure calcu
lations. The surface layer of molecules does not contribute to the met
allic conductivity for any bulk composition.