Wm. Sears et Da. Love, MEASUREMENTS OF THE ELECTRICAL MOBILITY OF SILVER OVER A HOT TIN OXIDE SURFACE, Physical review. B, Condensed matter, 47(19), 1993, pp. 12972-12975
We report on measurements of the drift mobility of silver ions on the
surface of tin oxide maintained at temperatures between 400 and 500-de
grees-C, in air. Silver contacts are placed on the surface arranged as
an inner circular anode and an outer concentric-ring cathode, and by
measuring silver advancement outward, mobility can be determined. Meas
urements were made as a function of temperature, field intensity, surf
ace roughness, and oxygen content of air. Drift-mobility values varied
from 10(-8) to 10(-5) cm2/V s. It seems from our results that the dyn
amic formation of surface oxide (silver oxide is unstable above 300-de
grees-C) is important in understanding silver migration.