NEW-TYPE CLATHRATE OF THE 3D METAL-COMPLEX HOST (N-METHYL-1,3-DIAMINOPROPANE)CADMIUM(II) TETRACYANOCADMATE(II)

Authors
KITAZAWA T
Citation
T. Kitazawa, NEW-TYPE CLATHRATE OF THE 3D METAL-COMPLEX HOST (N-METHYL-1,3-DIAMINOPROPANE)CADMIUM(II) TETRACYANOCADMATE(II), Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 276, 1996, pp. 167-172
Citations number
22
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
276
Year of publication
1996
Pages
167 - 172
Database
ISI
SICI code
1058-725X(1996)276:<167:NCOT3M>2.0.ZU;2-I
Abstract
A new clathrate compound Cd(mon)Cd(CN)(4) . Cl-ClCH2Cl (mtn = N-methyl -1,3-diaminopropane)is prepared and characterized to contain tetrahedr al and octahedral Cd atoms in a ratio of 1:1, mtn chelating to the lat ter. A pair of 1,2-dichloroethane guest molecules are accommodated in a cavity of the host framework. The arrangement of octahedral and tetr ahedral Cd atoms is different from that of the previously reported Cd( pn)Cd(CN)(4) . CH2ClCH2Cl (pn = 1,2-diaminopropane) which has the same composition.