FRIEDEL-CRAFTS REACTION OF TOLUENE WITH OXALYL CHLORIDE

Authors
SAKAINO Y SUGAWARA K TERAO Y FUJIWARA T MORI Y MAEDA K
Citation
Y. Sakaino et al., FRIEDEL-CRAFTS REACTION OF TOLUENE WITH OXALYL CHLORIDE, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 276, 1996, pp. 271-275
Citations number
4
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
276
Year of publication
1996
Pages
271 - 275
Database
ISI
SICI code
1058-725X(1996)276:<271:FROTWO>2.0.ZU;2-M
Abstract
By the Friedel-Crafts reaction of toluene with oxalyl chloride, three kinds of fluorene derivatives (c, d, e), naphthalene derivative f, flu orenone derivative g, were obtained in addition to 4,4'-dimethyl benzo phenone b.. In the compounds (c, d, e, f, g), c shows thermochromism a bove 135 degrees C in solution, while e emits phosphorescence and f ex hibits fluorescence at room temperature in the solid states.