STEREOSELECTIVE SYNTHESIS OF SULFINATES FROM MANNITOL DERIVED SULFITES

Authors
PELLOUXLEON N GAUTIERLUNEAU I WENDT S VALLEE Y
Citation
N. Pellouxleon et al., STEREOSELECTIVE SYNTHESIS OF SULFINATES FROM MANNITOL DERIVED SULFITES, Tetrahedron : asymmetry, 7(4), 1996, pp. 1007-1010
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
7
Issue
4
Year of publication
1996
Pages
1007 - 1010
Database
ISI
SICI code
0957-4166(1996)7:4<1007:SSOSFM>2.0.ZU;2-G
Abstract
The reaction of Grignard reagents with two mannitol derived sulfites h as been studied, High diastereoselectivity (96% d.e.) was achieved wit h t-BuMgCl and cyclohexylidene protected sulfite in THF in the presenc e of a Lewis acid. Copyright (C) 1996 Elsevier Science Ltd