SYNTHETIC APPLICATIONS OF FUNCTIONALIZED PHOSPHORANYLIDENEAMINO-1,4-BENZOQUINONES - PREPARATION OF OXAZOLO[5,4-B]PHENOXAZINE, 4H-[3,1]BENZCSXAZINO-5,8-QUINONE AND BENZOXAZOLE DERIVATIVES

Authors
RODRIGUEZMORGADE S VAZQUEZ P TORRES T
Citation
S. Rodriguezmorgade et al., SYNTHETIC APPLICATIONS OF FUNCTIONALIZED PHOSPHORANYLIDENEAMINO-1,4-BENZOQUINONES - PREPARATION OF OXAZOLO[5,4-B]PHENOXAZINE, 4H-[3,1]BENZCSXAZINO-5,8-QUINONE AND BENZOXAZOLE DERIVATIVES, Tetrahedron, 52(19), 1996, pp. 6781-6794
Citations number
50
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
19
Year of publication
1996
Pages
6781 - 6794
Database
ISI
SICI code
0040-4020(1996)52:19<6781:SAOFP>2.0.ZU;2-G
Abstract
The aza-Wittig reaction of the triphenylphosphoranylideneamino-1,4-ben zoquinone 1 with aryl isocyanates and aroyl chlorides allows the prepa ration of oxazolo[5,4-b]phenoxazine and benzoxazole derivatives. The s ame reaction using 7 as iminophosphoranoquinone provides substituted b enzoxazoles and the previously unreported 4H-[3,1]benzoxazino-5,8-quin ones. Copyright (C) 1996 Elsevier Science Ltd