OXIDATIVE COUPLING OF LITHIUM SILENOLATES - FIRST SYNTHESIS OF BIS(ACYL)-SUBSTITUTED POLYSILANES

Authors
OHSHITA J MASAOKA S ISHIKAWA M
Citation
J. Ohshita et al., OXIDATIVE COUPLING OF LITHIUM SILENOLATES - FIRST SYNTHESIS OF BIS(ACYL)-SUBSTITUTED POLYSILANES, Organometallics, 15(9), 1996, pp. 2198-2200
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
9
Year of publication
1996
Pages
2198 - 2200
Database
ISI
SICI code
0276-7333(1996)15:9<2198:OCOLS->2.0.ZU;2-0
Abstract
Treatment of lithium 2-meistyl-, adamantyl-, and tert-butyl-1,1-bis(tr imethylsilyl)-1-silen-2-olate with 0.5 equiv of palladium dichloride a fforded the corresponding coupling products, 1,2-bis(acyl)tetrakis(tri methylsilyl)disilanes (3a-c), in high yields. The molecular structure of compound 3b was established by single-crystal X-ray diffraction stu dy.