H. Leinonen, STRESS-CORROSION CRACKING AND LIFE PREDICTION EVALUATION OF AUSTENITIC STAINLESS-STEELS IN CALCIUM-CHLORIDE SOLUTION, Corrosion, 52(5), 1996, pp. 337-346
The stress corrosion cracking (SCC) susceptibility of austenitic stain
less steels (SS) in calcium chloride (CaCl2) solutions was Studied usi
ng a constant-load method. Initiation and propagation of stress corros
ion cracks were examined using fractography. The distribution of crack
s was classified A physical cracking was introduced, and creep deforma
tion measurements were performed. The steady-state strain rate (epsilo
n(ss)) obtained from the corrosion elongation curve (elongation-vs-tim
e curve) showed a linear function of time to failure (t(f)). This impl
ied that epsilon(ss) can be applied as a parameter for prediction of t
(f). Furthermore, epsilon(ss) below which no failure occurs within a l
aboratory time scale was estimated. Based on results obtained, the cri
tical values of stress (sigma) below which no SCC occurred were evalua
ted. Based upon creep measurements in a noncorrosive environment, the
influence of environment on epsilon(ss) was more than fivefold. Cracki
ng characteristics were divided into three categories according to the
crack initiation distribution Transgranular cracking predominated at
relatively low sigma and epsilon(ss).