Tm. Grehk et al., ADSORPTION OF POTASSIUM ON THE SI(111)ROOT-3X-ROOT-3R30-DEGREES - B-SURFACE - OBSERVATION OF AN INSULATING SURFACE AT SUBMONOLAYER COVERAGE, Physical review. B, Condensed matter, 47(20), 1993, pp. 13887-13890
The Si(111) square-root 3 X square-root 3R 30-degrees:B surface with s
ubmonolayer coverages of potassium has been studied with angle-resolve
d photoelectron spectroscopy. Deposition of potassium leads to the for
mation of a state 0.7 eV below the Fermi level. The energy position of
this state showed only a minor dependence on the actual potassium cov
erage and the state displayed a small dispersion of 0.1 eV when probed
along the GAMMABAR-MBAR' direction in the square-root 3 X square-root
3R 30-degrees-surface Brillouin zone. These results support the idea
that a mainly covalent bonding exists between the potassium atoms and
the Si surface.