MECHANISTIC PATHWAYS FOR RADICAL RING EXPANSION AROMATIZATION OF STEROID-C D MODELS/

Citation
Sp. Green et Da. Whiting, MECHANISTIC PATHWAYS FOR RADICAL RING EXPANSION AROMATIZATION OF STEROID-C D MODELS/, Journal of the Chemical Society. Perkin transactions. I, (11), 1993, pp. 1205-1206
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
0300922X
Issue
11
Year of publication
1993
Pages
1205 - 1206
Database
ISI
SICI code
0300-922X(1993):11<1205:MPFRRE>2.0.ZU;2-Y
Abstract
The pathway for ring expansion and aromatisation of the radical 9 to t he isomeric tetralins 7 and 10 (Scheme 2) has been investigated by deu terium labelling, and a new mechanism (Scheme 5) is put forward.