CARBENES IN CONSTRAINED SYSTEMS .4. ENCAPSULATION OF AN ASYMMETRIC DIAZIRINE - REACTIVITY OF 2-METHYLCYCLOHEXANYLIDENE

Authors
ROSENBERG MG KAM SM BRINKER UH
Citation
Mg. Rosenberg et al., CARBENES IN CONSTRAINED SYSTEMS .4. ENCAPSULATION OF AN ASYMMETRIC DIAZIRINE - REACTIVITY OF 2-METHYLCYCLOHEXANYLIDENE, Tetrahedron letters, 37(19), 1996, pp. 3235-3238
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
19
Year of publication
1996
Pages
3235 - 3238
Database
ISI
SICI code
0040-4039(1996)37:19<3235:CICS.E>2.0.ZU;2-Z
Abstract
2-Methylcyclohexanylidene was generated from the corresponding diaziri ne within the cavities of alpha-, beta- and gamma-cyclodextrin by phot olysis in the solid state. To surmise how these constrained systems af fect the residing carbene's selectivity, a comparison with conventiona l reaction methods was made. (C) 1996 Elsevier Science Ltd.