ASYMMETRIC-SYNTHESIS OF (DIENE)FE(CO)(3) COMPLEXES VIA CATALYTIC ENANTIOSELECTIVE ALKYLATION WITH DIALKYLZINC

Authors
TAKEMOTO Y BABA Y NOGUCHI I IWATA C
Citation
Y. Takemoto et al., ASYMMETRIC-SYNTHESIS OF (DIENE)FE(CO)(3) COMPLEXES VIA CATALYTIC ENANTIOSELECTIVE ALKYLATION WITH DIALKYLZINC, Tetrahedron letters, 37(19), 1996, pp. 3345-3346
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
19
Year of publication
1996
Pages
3345 - 3346
Database
ISI
SICI code
0040-4039(1996)37:19<3345:AO(CVC>2.0.ZU;2-D
Abstract
The reaction of meso-2,4-hexadien-1,6-dial Fe(CO)(3) complex 1 with se veral alkylzincs in the presence of 50 mol% of (S)-(+)-diphenyl-(1-met hylpyrrolidn-2-yl) methanol 4a proceeded with high enantiotopic group- and face-selectivity to give (2R,6S)-mono alcohol complexes 2a-c as m ajor products (>90% de and >98% ee). (C) 1996 Elsevier Science Ltd