Rf. Klevtsova et al., CRYSTAL-STRUCTURE INVESTIGATION OF TERNARY MOLYBDATE K-5(MN0.5ZR1.5)CENTER-DOT(MOO4)(6), Journal of structural chemistry, 36(5), 1995, pp. 813-817
Crystals of K-5(Mn0.5Zr1.5).(MoO4)(6) were grown, and the crystal stru
cture of this compound was refined in an X-ray diffraction study (CAD-
4 automatic diffractometer, MoKalpha radiation 1183 \F(hkl)\, R = 0.02
7). The parameters of the trigonal unit cell are: a = b = 10.584(1); c
= 37.576(3) Angstrom; V = 3645.4(3) Angstrom(3); space group R3c; d(c
alc) = 3.606 g/cm(3). In the structure, the alternating Mo tetrahedra
and (Mn, Zr) octahedra form a three-dimensional mixed framework whose
voids contain potassium atoms of three types. The distribution of the
Mn and Zr cations in two crystallographic positions has been refined.