S. Kuck et al., ELECTRONIC AND VIBRONIC TRANSITIONS OF THE CR4-DOPED GARNETS LU3AL5O12, Y3AL5O12, Y3GA5O12 AND GD3GA5O12(), Journal of luminescence, 68(1), 1996, pp. 1-14
The Cr4+-doped stoichiometric garnets Lu3Al5O12 (LAG), Y3Al5O12 (YAG),
Y3Ga5O12 (YGG), and Gd3Ga5O12 (GGG) are spectroscopically investigate
d. All of these crystals exhibit broadband absorption around 1 mu m an
d broadband emission in the spectral range between 1.1 and 1.8 mu m. A
t low temperatures zero-phonon transitions as well as pronounced phono
n sidebands are observed. The energies of the coupling phonons and the
spin-orbit splittings of the energy levels are analyzed in detail.