SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY OF DINUCLEAR IRON(III) AND RUTHENIUM(III) COMPLEXES

Authors
ANEETHA H PADMAJA J ZACHARIAS PS
Citation
H. Aneetha et al., SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY OF DINUCLEAR IRON(III) AND RUTHENIUM(III) COMPLEXES, Polyhedron, 15(14), 1996, pp. 2445-2451
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
14
Year of publication
1996
Pages
2445 - 2451
Database
ISI
SICI code
0277-5387(1996)15:14<2445:SCACAO>2.0.ZU;2-I
Abstract
A number of dinuclear iron(III) and ruthenium(III) complexes from dinu cleating ligands have been synthesised and characterized. The iron(III ) complexes of dinucleating triazene-1-oxide ligands (type 1) catalyse the epoxidation of alkenes with iodosyl benzene as an oxidant. The ca talytic activity of iron(III) complexes of dinucleating Schiff base li gands (type 2) could not be studied due to insolubility. Ruthenium(III ) complexes of both types of ligands catalyse epoxidation reactions. C opyright (C) 1996 Elsevier Science Ltd.