Tr. Park, A RELATIONSHIP BETWEEN SOUND SPEED AND A NONRADIATIVE RELAXATION PROCESS IN SODIUM CRYPTAND SODIDE, Solid state communications, 98(8), 1996, pp. 727-731
The wavefunction of the spatially extended excitonic state in sodium c
ryptand sodide is calculated in a semi-continuum approach. The magnitu
de of the lattice relaxation energy in a breathing mode induced by the
electronic charge redistribution is computed in terms of the wavefunc
tion. The sound speed in sodium cryptand sodide is estimated based on
the fact that the lattice relaxes sufficiently to have a nonradiative
deexcitation of the spatially extended state.