J. Daleiden et al., INGAASP INP 1.55-MU-M LASERS WITH CHEMICALLY ASSISTED ION BEAM-ETCHEDFACETS/, Optical and quantum electronics, 28(5), 1996, pp. 527-532
Chemically assisted ion beam etching (CAIBE) involving an Ar ion beam
and a halogen ambient gas (Cl-2, IBr3) has been used to etch high-qual
ity laser facets for InGaAsP/lnP bulk lasers (1.55 mu m). We achieved
etch rates of 40.0-75.0 nm min(-1) at substrate temperatures between -
5 and +10 degrees C. These low temperatures have allowed us to utilize
UV-baked photoresists as well as PMMA as etch masks, facilitating ver
y simple process development. Higher substrate temperatures (50 to 120
degrees C) yield still higher etch rates, but at the expense of sever
ely degraded surface morphologies. Angle resolved x-ray photoelectron
spectroscopy (XPS) was investigated for observing etched InP surfaces.
A disproportioned surface has been detected after etching in the high
er temperature range; low temperatures yield stoichiometric surfaces.