The synthesis of five (alpha and beta)2-naphthylchromones, with isolat
ion of the intermediates, both o-hydroxybenzoyl naphthoyl methanes and
o-acetylphenyl naphthoates, is reported. Eight compounds of the 15 pr
epared are novel. The esters were obtained in excellent yields under m
ild reaction conditions, the diones and target compounds in good yield
s. The H-1-NMR spectra of 13 of them and all C-13-NMR were recorded fo
r the first time.