Agj. Vanderham et al., PROPOSAL FOR A REGENERATIVE HIGH-TEMPERATURE PROCESS FOR COAL-GAS CLEANUP WITH CALCINED LIMESTONE, Industrial & engineering chemistry research, 35(5), 1996, pp. 1487-1495
This paper deals with a new regenerative, high-temperature process for
coal gas desulfurization using calcined limestone (CaO) as a sorbent.
The process includes three steps. First H2S reacts with CaO toward Ca
S (sulfidation), which is then partly oxidized with SO2 in a second st
ep to obtain CaSO4 and elemental sulfur. Finally, in a third step (reg
eneration) the solid mixture of CaS and CaSO4 remaining after the oxid
ation step is decomposed to produce CaO and SO2 which are both reused
in the first and second steps, respectively. The proposed process thus
yields elemental sulfur as the final product. Several sulfidation-oxi
dation-regeneration cycles (up to nine) were carried out in a thermogr
avimetric analyzer (TGA) using various calcined limestones. The result
s are promising, showing a constant absorption capacity of 30-50% from
two cycles on. On the basis of kinetic experiments and thermodynamic
considerations, the optimum temperatures were determined at 815-845 de
grees C for the desulfurization of Shell coal applicability of calcine
d limestone for nonregenerative HCl removal was examined. The reaction
between CaO and HCl was found to proceed fast enough to enable practi
cal application. The limestone utilization was found to vary from 8% a
t 200 degrees C to 80% at 600 degrees C.