Deuterated molecules in interstellar clouds constitute a unique source
of information on three interstellar parameters: the deuterium/hydrog
en abundance ratio [D]/[H], the fractional ionization in dense clouds,
and the galactic ionizing flux (Dalgarno & Lepp 1984, Millar 1990). T
he molecular ion H2D+ plays a key role in the formation of deuterated
molecules. Dissociative recombination with electrons is a major loss c
hannel and a potential source of deuterium atoms. An ion storage ring
has been used to obtain the total recombination rate coefficient, and
the probabilities for decay into H+H+D, HD+H and H-2+D. Using them in
a model of the cloud L1529 we derive from observational data on HCO+ a
nd DCO+ an upper limit to the fractional ionization of 2 x 10(-6), a [
D]/[H] ratio of 1.7 x 10(-5) and an atomic D/H ratio of 2.7 x 10(-3).