The microstructural changes induced in polycrystalline alpha-alumina b
y high dose ion implantation were studied by Transmission Electron Mic
roscopy (TEM) and X-ray Absorption Near-Edge Structure (XANES). Severa
l regions were observed in the specimens prepared by the cross-section
al method. We found that the implanted layer consists of a strongly da
maged crystallographic structure, which tends to be destabilized in a
cubic structure, where the atomic sites are very strained. The layer b
eyond the distribution of implanted ions is characterized by a high de
nsity of defects. A mechanism explaining the formation of this defecti
ve layer is proposed.