Nitrogen-atom behavior in a low-pressure, nonisothermal microwave-gene
rated nitrogen afterglow was studied. N-atom flux was measured by chem
ical titration. It was found that an increase in power or flow rate, o
r a decrease in pressure resulted ill larger productions of N atoms. A
one-dimensional mass-continuity equation was used to model N atoms' c
oncentration field in the afterglow. The model, with no adjustable par
ameters, agreed closely with experimental measurements. The model show
s that convection, diffusion, and wall recombination play important ro
les in the afterglow. In contrast, N-atom generation and homogeneous r
ecombination are of marginal importance. The model was manipulated to
assess the impact of the measuring technique, chemical titration, on t
he N-atom flux. It was found that the N-atom flux profile is only slig
htly impacted, although the concentration profile is strongly modified
.